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    • 专利摘要:
    summary patent of invention: "hot rolled steel sheet". the present invention relates to a hot rolled steel sheet includes a specified chemical composition and includes a steel structure represented by a ferrite area ratio of 5% to 50%, a bainite area ratio composed of an aggregate of bainitic ferrite whose average grain disorientation is 0.4 ° to 3 ° with 50% to 90%, and the total area ratio of martensite, perlite and austenite retained being 5% or less.
    公开号:BR112015024840B1
    申请号:R112015024840-3
    申请日:2014-04-14
    公开日:2020-03-31
    发明作者:Yuri Toda；Masafumi Azuma；Akihiro Uenishi；Genichi Shigesato
    申请人:Nippon Steel Corporation；
    IPC主号:
    专利说明:

    Descriptive Report of the Invention Patent for HOT LAMINATED STEEL SHEET.
    Technical field [001] The present invention relates to an excellent hot-rolled steel sheet in elongation and a bore expansion capacity.
    Background [002] The weight reduction of a car's chassis using a high-strength steel plate has been proposed to suppress the amount of carbon dioxide gas emitted by a car. A sheet of high-strength steel has often been used for a chassis to also ensure the safety of a passenger. In addition, the improvement in strength is important to also cause the weight reduction of a chassis. In addition, the improvement of resistance is important, it is also important to cause the weight reduction of the chassis. On the other hand, some parts of a chassis require excellent forming capabilities. For example, excellent hole expansion capacity is required for a high strength steel plate for a lower part of the chassis.
    [003] However, achieving both improved strength and improved forming capacity is difficult. In general, the greater the strength of a steel plate, the lower the forming capacity, and the elongation, which is important in stamping and internal expansion, and the hole expansion capacity, which is important in deburring, are reduced.
    [004] Patent Literature 1 to 11 describe high strength steel sheets for the purpose of improving forming capacity or something. However, a hot-rolled steel sheet having sufficient strength and sufficient forming capacity cannot be obtained by conventional techniques.
    Petition 870170016959, of 03/15/2017, p. 4/53
    2/47 [005] Although a technique for improving hole expansion capacity is described in Non-Patent Literature 1, a hot rolled steel sheet having sufficient strength and sufficient forming capacity cannot be obtained by this conventional technique. In addition, this conventional technique is difficult to apply to an industrial scale production process for hot-rolled steel sheet.
    List of citations
    Patent Literature
    Patent
    Japanese [006] Patent Literature 1: Publication open to public inspection No. 2012-26032 [007] Patent Literature 2: Publication open to public inspection No. 2011-225941 [008] Patent Literature 3: Publication open to public inspection No. 2006-274318 [009] Patent Literature 4: Publication open to public inspection No. 2005-220440 [0010] Patent Literature 5: Publication open to public inspection No. 2010-255090 [0011] Patent Literature 6: Publication open to public inspection No. 2010-202976 [0012] Patent Literature 7: Publication open to public inspection No. 2012-62561 [0013] Patent Literature 8: Publication open to public inspection No. 2004-218077 [0014] Literature of Patent 9: Publication open to public inspection No. 2005-82841 [0015] Patent Literature 10: Japanese Patent publication open to public inspection No. 2007-314828 [0016] Patent Literature 11: Japanese Patent publication d and of
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    Petition 870170016959, of 03/15/2017, p. 5/53
    3/47 open to public inspection No. 2002-534601
    Non-Patent Literature [0017] Non-Patent Literature 1: Kato et al., Seitetsukenkyu (1984) vol. 312, p.41 Summary of the invention Technical problem [0018] A purpose of the present invention is to provide a hot rolled steel sheet having a high strength and which is capable of obtaining excellent elongation and bore expansion capacity. Solution to the problem [0019] The inventors of the present application, with attention to the general production method of a hot rolled steel sheet implemented on an industrial scale using a common continuous hot rolling mill, conducted intensive studies to improve the capacity conformation such as elongation and hole expansion capacity of hot rolled steel sheet while achieving high strength. As a result, a new structure was found to be very effective in guaranteeing high strength and improving forming capacity, the structure not having been formed by a conventional technique. This structure is bainite composed of an aggregate of bainitic ferrite whose average grain disorientation is 0.4 ° or more to 3 ° or less. This bainite hardly contains carbides and austenite retained in a grain. In other words, this bainite hardly contains what promotes the development of a fracture in the hole expansion. Thus, this bainite contributes to ensure high strength and improved elongation and hole expansion capacity.
    [0020] Bainite composed of the aggregate of bainitic ferrite whose average grain disorientation is 0.4 ° or more at 3 ° or less is not capable of being formed by a conventional method such as methods
    Petition 870170016959, of 03/15/2017, p. 6/53
    4/47 described above in Patent Literature 1 to 11. For example, the above bainite cannot be formed by a conventional technique that aims to increase resistance by forming martensite by making the cooling rate higher since the end of the so-called cooling intermediate air for coiling. For example, the bainite included in a conventional steel sheet is composed of bainitic ferrite and an iron carbide, or composed of retained austenite and bainitic ferrite. Thus, in conventional steel plate, iron carbide or retained austenite (or martensite having been transformed when being processed) promotes the development of a fracture in the hole expansion. Consequently, bainite composed of the aggregate of bainitic ferrite whose average grain disorientation is 0.4 ° or more at 3 ° or less has a bore expansion capacity greater than that of bainite included in a conventional steel plate. This bainite is a different structure also from the ferrite included in a conventional steel plate. For example, the generation temperature of this bainite is equal to or less than the starting temperature of the transformation of the bainite estimated from a steel component, and the grain edge at a low angle exists within a grain surrounded by an edge high angle grain of this bainite. This bainite has a different characteristic from that of ferrite at least in the points above.
    [0021] With the details being described later, the inventors of the present application have found that by making the conditions for finishing lamination, after cooling, after winding, after cooling, etc., be suitable, bainite can be formed with a desired area ratio along with the ferrite. By the methods described in Patent Literature 1 to 3, it is impossible to form bainite having a low angle grain border within a grain surrounded by a high angle grain border,
    Petition 870170016959, of 03/15/2017, p. 7/53
    5/47 as long as the cooling rate after the end of the intermediate air cooling and before winding, and the cooling rate in the coil state are quite high.
    [0022] The inventors of the present application have also conducted
    intense studies based on the above observation, and devised modalities of the invention described below.
    (1) [0023] by C: A hot rolled steel sheet including: a chemical composition represented, in% by mass,0.02% to 0.15%, Si: 0.01% to 2.0%, Mn: 0.05% to 3.0%, P: 0.1% or less, S: 0.03% or less, Al: 0.001% to 0.01%, N: 0.02% or less, THE: 0.02% or less, You: 0% to 0.2%, Nb: 0% to 0.2% Mo: 0% to 0.2% V: 0% to 0.2% Cr: 0% to 1.0%, B: 0% to 0.01%, Ass: 0% to 1.2%, Ni: 0% to 0.6%, Here: 0% to 0.005%, REM: 0% to 0.02%, and the balance: Fe and impurities; and [0024][0025] a steel structure represented by a ferrite area ratio: 5% to 50%,
    Petition 870170016959, of 03/15/2017, p. 8/53
    6/47 [0026] a bainite area ratio composed of a bainitic ferrite aggregate whose average grain disorientation is 0.4 ° to 3 °: 50% to 95%, and [0027] a total area ratio of martensite , perlite and retained austenite: 5% or less.
    (2) The hot-rolled steel sheet according to item (1), in which the chemical composition satisfies one or more elements selected from the group consisting of, in% by mass,
    Ti: 0.01% to 0.2%,
    Nb: 0.01% to 0.2%,
    Mo: 0.001% to 0.2%,
    V: 0.01% to 0.2%,
    Cr: 0.01% to 1.0%,
    B: 0.0002% to 0.01%,
    Cu: 0.02% to 1.2%, and
    Ni: 0.01% to 0.6%.
    (3) The hot-rolled steel sheet according to item (1) or (2), in which the chemical composition satisfies one or more elements selected from the group consisting of, in% by mass,
    Ca: 0.0005% to 0.005% and
    REM: 0.0005% to 0.02%.
    Advantageous effects of the invention [0028] According to the present invention, it is possible to obtain excellent elongation and bore expansion capacity while having a high strength.
    Brief description of the drawings [0029] Figure 1 is a view illustrating a region representing a steel structure of a hot-rolled steel sheet, and [0030] Figure 2 is a view illustrating an outline of the temperature history since rolling hot until winding.
    Petition 870170016959, of 03/15/2017, p. 9/53
    7/47
    Description of Modalities [0031] Hereinafter, an embodiment of the present invention will be described.
    [0032] Initially, the steel structure of a hot rolled steel sheet according to the present modality will be described. The hot-rolled steel sheet according to the present modality includes a steel structure represented by a ferrite area ratio: 5% to 50%, a bainite area ratio composed of a bainitic ferrite aggregate whose average grain disorientation is 0.4 ° to 3 °: 50% to 95%, a total area ratio of martensite, perlite and austenite retained: 5% or less. The steel structure of the hot-rolled steel sheet can be represented by a steel structure in a region between 3/8 and 5/8 of the thickness of the hot-rolled steel sheet from its surface. This region 1 is illustrated in Figure 1. A cross section 2 that is the object of observation of the steel structure is also illustrated in Figure 1.
    (Ferrite area ratio: 5% to 50%) [0033] Ferrite exhibits excellent ductility and increases uniform elongation. When the ferrite area ratio is less than 5%, good uniform elongation cannot be achieved. Therefore, the ferrite area ratio is 5% or more. When the ferrite area ratio is above 50%, the hole expansion capacity is reduced considerably. Thus, the ferrite area ratio is 50% or less. The ferrite area ratio is an area ratio in the cross section 2 parallel to the rolling direction in the region between 3/8 and 5/8 of the thickness of the hot-rolled steel sheet from its surface, and is a ratio of ferrite area in a microstructure observed at a magnification of 200 to 500 times using an optical microscope. (Area ratio of bainite composed of aggregate of bainitic ferrite whose average grain disorientation is 0.4 ° to 3 ° 50% to 95%)
    Petition 870170016959, of 03/15/2017, p. 10/53
    8/47 [0034] The bainite composed of the aggregate of bainitic ferrite whose average grain disorientation is 0.4 ° or more at 3 ° or less is a new structure obtained by a method described later. The average grain disorientation is obtained as follows. Initially, crystal orientations of some points in cross section 2 are measured by an “electron back scattering diffraction” (EBSD) method. Then, based on the results of the EBSD measurement, it is assumed that an edge of the grain exists between two points (pixels) that are adjacent to each other and between which a disorientation of the crystal is 15 ° or more. Then, within a region surrounded by the edge of the grain, that is, within the grain, the disorientations of the crystal between points adjacent to each other are calculated, and its average value is calculated. The average disorientation of the grain within a crystal grain is obtained in this way.
    [0035] As described above, it was discovered by the inventors of the present application that bainite composed of the aggregate of bainitic ferrite whose average grain disorientation is 0.4 ° or more 3 ° or less is a very effective structure to ensure high strength and the improvement of forming capacity such as hole expansion capacity. This bainite hardly contains carbides and austenite retained in the grain. In other words, this bainite hardly contains what promotes the development of a fracture in the hole expansion. Therefore, this bainite contributes to ensure high strength and improved elongation and hole expansion capacity.
    [0036] When the area ratio of the bainite composed of the aggregate of bainitic ferrite whose average grain disorientation is 0.4 ° or more at 3 ° or less is less than 50%, a sufficient strength cannot be obtained. Therefore, the area ratio of this bainite is 50% or more. When the area ratio of this bainite is above 95%, sufficient elongation cannot be achieved. Therefore, the area ratio of this bainite is 95% or less. When the area ratio of this bainite
    Petition 870170016959, of 03/15/2017, p. 11/53
    9/47 is 50% or more to 95% or less, usually the tensile strength is 590 MPa or more, a product (TS x λ) of the tensile strength (TS (MPa)) for the bore expansion ratio (λ (%)) is 65000 or more, and a product (EL x λ) of the total elongation (EL (%)) for the hole expansion ratio (λ (%)) is 1300 or more. These characteristics are suitable for processing a lower part of an automobile chassis.
    [0037] A grain whose average grain disorientation is less than 0.4 ° can be considered as ferrite. A grain whose average grain disorientation is above 3 ° is lower in hole expansion capacity. The grain whose average grain disorientation is above 3 ° is generated in a temperature zone below that of the bainite composed of the bainitic ferrite aggregate whose average grain disorientation is 0.4 ° or more at 3 ° or less, for example.
    (Total area ratio of martensite, perlite and retained austenite: 5% or less) [0038] Martensite, perlite, and retained austenite promote the development of a fracture at an interface with ferrite or bainite in the bore expansion, and reduces the capacity hole expansion. When the total area ratio of martensite, perlite, and austenite retained is above 5%, such deterioration in the hole expansion capacity is prominent. The area ratios of perlite, martensite, and austenite retained are each the area ratios in cross-section 2, and the area ratios of perlite, martensite and austenite retained in a microstructure observed at a magnification of 200 to 500 times using an optical microscope. When the total of these structures is 5% or less, generally the product (EL x λ) of the total elongation (EL (%)) for the bore expansion ratio (λ (%)) is above 1300, it is suitable for processing the lower part of the car chassis.
    [0039] It is logical that it is preferable that a condition relating to the reason
    Petition 870170016959, of 03/15/2017, p. 12/53
    10/47 of the aforementioned area of each structure is satisfied not only in region 1 but also in a wider range, and the wider the range where this condition is met, the more excellent strength and work capacity can be obtained. [0040] The chemical composition of the hot-rolled steel sheet according to the mode of the present invention will be described below. In the description that follows,% which is the unit of the content of each element contained in the hot-rolled steel sheet means% by mass unless otherwise mentioned. The hot rolled steel sheet according to the present modality includes a chemical composition represented by C: 0.02% to 0.15%, Si: 0.01% to 2.0%, Mn: 0.05% to 3, 0%, P: 0.1% or less, S: 0.03% or less, Al: 0.001% to 0.01%, N: 0.02% or less, O: 0.02% or less, Ti : 0% to 0.2%, Nb: 0% to 0.2%, Mo: 0% to 0.2%, V: 0% to 0.2%, Cr: 0% to 1.0%, B : 0% to 0.01%, Cu: 0% to 1.2%, Ni: 0% to 0.6%, Ca: 0% to 0.005%, REM: 0% to 0.02%, and the balance : Fe and impurities. As impurities are exemplified what is included in a raw material such as ore and scrap and what is included in a production process.
    (C: 0.02% to 0.15%) [0041] C secretes at the grain edge and has the effect of suppressing peeling at one end of the surface by cutting or perforating. C binds to Nb, Ti or similar and forms a precipitate in the hot rolled steel sheet, contributing to the improvement of resistance by reinforcing precipitation. When the C content is less than 0.02%, the effect of suppressing peeling and the effect of improving resistance by reinforcing precipitation cannot be achieved sufficiently. Therefore, the C content is 0.02% or more. On the other hand, C generates an iron-based carbide such as cementite (Fe3C), martensite and retained austenite to be the starting point of a fracture in the bore expansion. When the C content is greater than 0.15%, the
    Petition 870170016959, of 03/15/2017, p. 13/53
    11/47 sufficient hole expansion capacity cannot be obtained. Therefore, the C content is 0.15% or less.
    (Si: 0.01% to 2.0%) [0042] Si contributes to the improvement of the resistance of the hot rolled steel sheet. It also has the role of deoxidizing material in molten steel. It suppresses precipitation of an iron-based carbide such as cementite and suppresses precipitation of cementite at the edge of bainitic ferrite. When the Si content is less than 0.01%, the above effects cannot be achieved sufficiently. Therefore, the Si content is 0.01% or more. When the Si content is above 2.0%, the effect to suppress cementite precipitation is saturated. In addition, when the Si content is above 2.0%, the generation of ferrite is suppressed, so that a desired steel structure in which the ferrite area ratio is 5% or more cannot be obtained. Therefore, the Si content is 2.0% or less.
    (Mn: 0.05% to 3.0%) [0043] Mn contributes to the improvement of strength by reinforcing the solid solution. When the Mn content is less than 0.05%, sufficient strength cannot be achieved. Therefore, the Mn content is 0.05% or more. When the Mn content is above 3.0%, a plaque fracture occurs. Therefore, the Mn content is 3.0% or less.
    (P: 0.1% or less) [0044] P is not an essential element and is contained as an impurity in steel, for example. In view of the workability, the weldability and the fatigue characteristic, as low a P content as possible is preferable. In particular, when the P content is above 0.1%, the deterioration in working capacity, weldability and fatigue characteristics is prominent. Therefore, the P content is 0.1% or less.
    (S: 0.03% or less)
    Petition 870170016959, of 03/15/2017, p. 14/53
    12/47 [0045] S is not an essential element and is contained as an impurity in steel, for example. A higher S content makes it easier for an A-based inclusion to lead to deterioration of the bore expansion capacity to be generated, and thus as low an S content as possible is preferable. In particular, when the S content is above 0.03%, the deterioration of the hole expansion capacity is prominent. Therefore, the S content is 0.03% or less.
    (Al: 0.001% to 0.01%) [0046] Al has an action to deoxidize the molten steel. When the Al content is less than 0.001%, sufficient deoxidation is difficult. Therefore, the Al content is 0.001% or more. When the Al content is above 0.01%, the elongation is easy to be reduced due to the increase in non-metallic inclusions. Therefore, the Al content is 0.01% or less.
    (N: 0.02% or less) [0047] N is not an essential element and is contained as an impurity in steel, for example. In view of the workability, an N content as low as possible is preferable. In particular, when the N content is above 0.02%, the deterioration in working capacity is prominent. Therefore, the N content is 0.02% or less.
    (O: 0.02% or less) [0048] O is not an essential element and is contained as an impurity in steel, for example. In view of the workability, an O content as low as possible is preferable. In particular, when the O content is above 0.02%, the deterioration in working capacity is prominent. Therefore, the O content is 0.02% or less.
    [0049] Ti, Nb, Mo, V, Cr, B, Cu, Ni, Ca, and REM are not essential elements but arbitrary elements, which may be contained
    Petition 870170016959, of 03/15/2017, p. 15/53
    13/47 on the hot-rolled steel sheet up to the limits of predetermined levels.
    [0050] (Ti: 0% to 0.2%, Nb: 0% to 0.2%, Mo: 0% to 0.2%, V: 0% to 0.2%, Cr: 0% to 1 , 0%, B: 0% to 0.01%, Cu: 0% to 1.2%, Ni: 0% to 0.6%) [0051] Ti, Nb, Mo, V, Cr, B, Cu , and Ni also contribute to improving the strength of the hot rolled steel sheet by hardening the precipitation or reinforcing the solid solution. Therefore, one or more elements selected from the group consisting of those elements may be contained. However, in relation to Ti, Nb, Mo, and V, when the content of any one of them is above 0.2%, the generation of ferrite is suppressed, so that the desired steel structure in which the area ratio of ferrite is 5% or more cannot be obtained. Therefore, the Ti content, the Nb content, the Mo content, and the V content are each 0.2% or less. When the Cr content is above 1.0%, the effect of improving strength is saturated. In addition, when the Cr content is above 1.0%, the generation of ferrite is suppressed, so that the desired steel structure in which the ferrite area ratio is 5% or more cannot be obtained. Therefore, the Cr content is 1.0% or less. When the B content is above 0.01%, the generation of ferrite is suppressed, so that the desired steel structure in which the ferrite area ratio is 5% or more cannot be obtained. Therefore, the B content is 0.01% or less. When the Cu content is above 1.2%, the generation of ferrite is suppressed, so that the desired steel structure in which the ferrite area ratio is 5% or more cannot be obtained. Therefore, the Cu content is 1.2% or less. When the Ni content is above 0.6%, the generation of ferrite is suppressed, so that the desired steel structure in which the ferrite area ratio is 5% or more cannot be obtained. Therefore, the Ni content is 0.6% or less. To guarantee a more excellent resistance of the hot rolled steel sheet, the Ti content, the Nb content, the V content, the Cr content, and the
    Petition 870170016959, of 03/15/2017, p. 16/53
    14/47
    Ni are each preferably 0.01% or more, the Mo content is preferably 0.001% or more, the B content is preferably 0.0002%, and the Cu content is preferably 0.02% or more. In other words, it is preferable that at least one among Ti: 0.01% to 0.2%, Nb: 0.01% to 0.2%, Mo: 0.001% to 0.2%, V: 0.01 % to 0.2%, Cr: 0.01% to 1.0%, B: 0.0002% to 0.01%, Cu: 0.02% to 1.2%, and Ni: 0.01% 0.6% is satisfied.
    (Ca: 0% to 0.005%, REM: 0% to 0.02%) [0052] Ca and REM change the shape of a non-metallic inclusion that can be a starting point of destruction or deteriorate [0053] the ability to work, and make non-metallic inclusions harmless. Therefore, one or more elements selected from the group consisting of the above elements may be contained. However, when the Ca content is above 0.005%, the shape of the non-metallic inclusion is elongated, and the non-metallic inclusion can be the starting point of destruction or deteriorate the work capacity. When the REM content is above 0.02%, the shape of the non-metallic inclusion is elongated and the non-metallic inclusion can be the starting point of destruction or deteriorate the work capacity. Therefore, the Ca content is 0.005% or less and the REM content is 0.02% or less. To make the most excellent non-metallic inclusions harmless, the Ca content and the REM content are each preferably 0.0005% or more. In other words, it is preferable that at least one between Ca: 0.0005% to 0.005% and REM: 0.0005% to 0.02% is satisfied.
    [0054] REM (rare earth metal) indicates elements of 17 types in total between Sc, Y, and lantanoids, and the REM content means the content of a total of these 17 types of elements. Lantanoids are added industrially in the form of metal misch, for example.
    [0055] The following will describe an example of a method for
    Petition 870170016959, of 03/15/2017, p. 17/53
    15/47 produce the hot-rolled steel sheet in accordance with this modality. Although the hot-rolled steel sheet in accordance with the present embodiment can be produced by the method described herein, a method for producing the hot-rolled steel sheet in accordance with the present embodiment is not limited thereto. In other words, even if the hot rolled steel sheet is produced by another method, as long as the hot rolled steel sheet includes the steel structure and chemical composition described above, the hot rolled steel structure can be considered as being within the scope of the modality. For example, although a seven-pass hot rolling mill is used in the following method, hot rolling produced using a six-pass hot rolling mill may sometimes fall within the scope of the present embodiment.
    [0056] In this method, the following steps are performed in sequence. Figure 2 illustrates an outline of the temperature history from hot rolling to winding.
    (1) A steel billet or plate including the chemical composition described above is billet, and reheating 11 is carried out as needed.
    (2) Roughing rolling 12 of the steel billet or plate is carried out. The rough rolling is included in the hot rolling.
    (3) Finishing lamination 13 of the steel billet or plate is carried out. The finishing lamination is included in the hot lamination. In finishing lamination, lamination of a pass before lamination of a final step is performed at a temperature of 850 ° C or more at 1150 ° C or less and a reduction of 10% or more to 40% or less, and the lamination of the final step is carried out at a temperature (T1 (° C)) of 850 ° C or more up to 1050 ° C or less and the
    Petition 870170016959, of 03/15/2017, p. 18/53
    16/47 a reduction of 3% or more up to 10% or less.
    (4) Cooling is performed on an output table up to a temperature (T2 (° C)) of 600 ° C or more up to 750 ° C or less. The time from the end of the finishing laminate to the start of cooling is indicated as t1 (seconds).
    (5) Air cooling 14 is performed for a time (t2 (seconds)) of 1 second or more up to 10 seconds or less. During this air cooling, ferrite is transformed into a two-phase region, and excellent elongation can be achieved.
    (6) Cooling 15 is performed at a cooling rate of P (° C / s) to a temperature of 400 ° C or more to 650 ° C or less. The cooling rate P meets (formula 1) below.
    (7) Winding 16 is performed at a temperature of 400 ° C or more up to 650 ° C or less.
    (8) The hot rolled coil is cooled at a cooling rate of 0.15 ° C / minute or less, while the temperature of the hot rolled coil is T3 (° C) - 300 ° C or more up to T3 ( ° C) or less. T3 (° C) is represented by (formula 2) below.
    (9) Cooling is performed from a temperature of less than T3 (° C) - 300 ° C to 25 ° C at a cooling rate of 0.05 ° C / minute or less.
    [0057] P (° C / s)> 1 / {1.44 x 10 12 exp (-3211 / (T1 + 273)) x t1 1/3 } x 2 x 10 11 + (C) x 1 / { 1 - (1.44 x 10 12 exp (-3211 / (T2 + 273)) x t2 1/3 } x (-3) x 10 13 (formula 1) [0058] T3 (° C) = 830 - 270 x (C) - 90 x (Mn) - 37 x (Ni) - 70 x (Cr) 83 x (Mo) (formula 2) [0059] Here, (C), (Mn), (Ni), (Cr ), and (Mo) indicate the C content, the Mn content, the Ni content, the Cr content, and the Mo content of a hot-rolled steel sheet, respectively.
    [0060] In the casting of the steel billet or plate, the molten steel
    Petition 870170016959, of 03/15/2017, p. 19/53
    17/47 whose components are adjusted to have a chemical composition within the range described above, is cast. Then, the steel billet or plate is sent to a hot rolling mill. On that occasion, the steel ingot or ingot plate having a high temperature can be sent directly to the hot rolling mill, or it can be cooled to room temperature and then reheated in a heating oven, and sent to the hot rolling mill. . The reheat temperature is not particularly limited. When the reheat temperature is 1260 ° C or more, the amount of surface oxidation increases and sometimes reduces the yield, and thus the reheat temperature is preferably less than 1260 ° C. In addition, when the reheat temperature is less than 1000 ° C, an efficiency of the operation is sometimes significantly impaired in terms of programming, and thus the reheat temperature is preferably 1000 ° C or more.
    [0061] When the lamination temperature of the final roughing lamination stage is less than 1080 ° C, that is, when the lamination temperature is decreased to less than 1080 ° C during the roughing lamination, an austenite grain after the finishing lamination becomes excessively small and the transformation from austenite to ferrite is promoted excessively, so that the desired bainite is sometimes difficult to obtain. Therefore, the lamination of the final step is preferably carried out at 1080 ° C or more. When the lamination temperature of the final roughing lamination step is above 1150 ° C, that is, when the lamination temperature exceeds 1150 ° C during roughing lamination, an austenite grain after the finishing lamination becomes large and the transformation of ferrite in a two-phase region to occur in the last cooling is not sufficiently promoted, so the steel structure wants to
    Petition 870170016959, of 03/15/2017, p. 20/53
    18/47 da is sometimes difficult to obtain. Therefore, the lamination of the final step is preferably carried out at 1150 ° C or less.
    [0062] When the cumulative reduction of the final step and its previous rough rolling mill step is above 65%, an austenite grain after the finishing mill becomes excessively small, and the transformation from austenite to ferrite is excessively promoted, so the desired bainite is sometimes difficult to obtain. Therefore, the cumulative reduction is preferably 65% or less. When the cumulative reduction is less than 40%, the austenite grain after the finishing lamination becomes large and the transformation of ferrite in the two-phase region occurs in the last cooling is not promoted sufficiently, so that the desired steel structure is sometimes difficult to obtain. Therefore, the cumulative reduction is preferably 40% or more.
    [0063] Finishing lamination is important for generating bainite composed of an aggregate of bainitic ferrite whose average grain disorientation is 0.4 ° or more at 3 ° or less. Bainitic ferrite can be obtained as a result of the fact that austenite which includes a stress after being processed is transformed into bainite. Therefore, it is important to perform the finishing lamination under a condition that makes the tension remain in the austenite after the finishing lamination.
    [0064] In the finishing lamination, a one-pass lamination before the final stage lamination, the final stage lamination being performed in a final chair of a finishing lamination laminator, is performed at a temperature of 850 ° C or more at 1150 ° C or less and a reduction of 10% or more to 40% or less. When the lamination temperature of the above lamination is above 1150 ° C or the reduction is less than 10%, the austenite grain after the finishing lamination becomes large, and the transformation of ferrite in the two-phase region to occur in the last cooling is
    Petition 870170016959, of 03/15/2017, p. 21/53
    19/47 is not promoted sufficiently, so that the desired steel structure cannot be obtained. When the lamination temperature of the above lamination is less than 850 ° C or the reduction is greater than 40%, the tension remains excessively in the austenite after the finishing lamination, and the workability is deteriorated.
    [0065] In finishing lamination, the lamination of the final step is carried out at a temperature of 850 ° C or more at 1050 ° C or less and at a reduction of 3% or more to 10% or less. The temperature (final temperature of the finishing lamination) of the final stage lamination is indicated as T1 (° C). When the temperature T1 is above 1050 ° C or the reduction is less than 3%, the residual amount of tension in the austenite after the finishing lamination becomes insufficient, so that the desired steel structure cannot be obtained. When the temperature T1 is less than 850 ° C or the reduction is above 10%, the tension remains excessively in the austenite after the finishing lamination, so that the working capacity is deteriorated.
    [0066] After finishing lamination, cooling is performed on an output table (ROT) up to a temperature of 600 ° C or more at 750 ° C or less. The temperature of the above cooling range is indicated as T2 (° C). When the temperature T2 is less than 600 ° C, the transformation of ferrite in the two-phase region becomes insufficient, so that sufficient elongation cannot be obtained. When the temperature T2 is above 750 ° C, the transformation of ferrite is excessively promoted, so that the desired steel structure cannot be obtained. The average cooling rate on the exit table is 20 ° C / s to 200 ° C / s, for example. This is to stably obtain the desired steel structure.
    [0067] Once the cooling on the exit table has finished, air cooling is performed for one second or more to ten seconds
    Petition 870170016959, of 03/15/2017, p. 22/53
    20/47 of or less. The air-cooling time is indicated as t2 (seconds). When the time t2 is less than one second, the transformation of ferrite in the two-phase region becomes insufficient, so that sufficient elongation cannot be obtained. When time t2 is over 10 seconds, the transformation of ferrite in the two-phase region is promoted excessively, so that the desired steel structure cannot be achieved.
    [0068] The time from the end of the finishing lamination to the start of cooling on the output table is indicated as t1 (seconds). The time t1 is not particularly limited, but it is preferably 10 seconds or less to prevent the austenite from becoming stiff after finishing lamination. Air cooling is substantially performed from the end of the finishing laminate to the start of cooling at the exit table.
    [0069] Once the air cooling for time t2 ends, cooling is performed to a temperature of 400 ° C or more at 650 ° C or less at a predetermined cooling rate. The cooling rate is indicated as P (° C / s). The cooling rate P satisfies the ratio of (formula 1). When the cooling rate P satisfies the ratio of (formula 1), the generation of perlite in air cooling can be suppressed, and the area ratios of martensite, perlite, and retained austenite can be made 5% or less in total. On the other hand, when the cooling rate P does not satisfy the ratio of (formula 1), the perlite is generated in large quantities, for example, so that the desired steel structure cannot be obtained. Therefore, the cooling rate P that satisfies the ratio of (formula 1) is very important to obtain the desired steel structure.
    [0070] The cooling rate P is preferably 200 ° C / s or less from the point of view of suppression of deformation due to thermal stress, etc. The cooling rate P is most preferably
    Petition 870170016959, of 03/15/2017, p. 23/53
    21/47
    30 ° C / s or less from the point of view of additional deformation suppression, etc.
    [0071] Thereafter, winding is performed at a temperature of 400 ° C or more at 650 ° C or less. When the winding temperature is above 650 ° C, ferrite is generated and sufficient bainite cannot be obtained, so that the desired steel structure cannot be obtained. When the winding temperature is less than 400 ° C, martensite is generated and sufficient bainite cannot be obtained, so that the desired steel structure cannot be obtained.
    [0072] While the temperature of the hot rolled coil obtained by winding is T3 (° C) - 300 ° C or more at T3 (° C) or less, the hot rolled coil is cooled at a cooling rate of 0, 15 ° C / minute or less. When the cooling rate is 0.15 ° C / minute at least, the transformation of bainite can be promoted, and the area ratios of martensite, perlite, and retained austenite can be made 5% or less in total. On the other hand, when the cooling rate is above 0.15 ° C / minute, the transformation of bainite is not promoted sufficiently, and the area ratios of martensite, perlite, and retained austenite exceed 5% in total, so that work capacity is deteriorated. Therefore, the cooling rate being 0.15 ° C / minute or less is very important to obtain the desired steel structure.
    [0073] When the temperature of the hot rolled coil exceeds the temperature T3 (° C), the transformation from austenite to perlite occurs, so that the desired steel structure cannot be obtained.
    [0074] When the temperature of the hot rolled coil is less than T3 (° C) - 300 ° C, the hot rolled coil is cooled at a cooling rate of 0.05 ° C / minute or less. When the cooling rate is 0.05 ° C / minute or less, the transformation from untransformed austenite to martensite can be suppressed, so that
    Petition 870170016959, of 03/15/2017, p. 24/53
    22/47 a higher working capacity can be obtained. On the other hand, when the cooling rate is above 0.05 ° C / minute, the transformation from austenite to martensite occurs, the area ratios of martensite, perlite and retained austenite exceed 5% in total, so that the capacity of work is deteriorated. In addition, during cooling, when the temperature of the hot rolled coil increases to exceed T3 (° C) - 300 ° C due to the generation of heat concomitant with the transformation from austenite to bainite phase, the transformation from austenite to perlite occurs and the structural fraction of perlite exceeds 5%, so that the work capacity is deteriorated.
    [0075] Even if the hot rolled steel sheet according to the present modality is subjected to a surface treatment, effects of improving the resistance, elongation, and the ability to expand the hole can be obtained. For example, electrocoating, hot dipping, deposition coating, organic coating formation, film lamination, treatment with organic salts, treatment with inorganic salts, treatments without chromium, or the like can be performed.
    [0076] The modality described above illustrates merely concrete examples of implementation of the present invention, and the technical scope of the present invention should not be construed in a restrictive manner by these modalities. That is, the present invention can be implemented in several ways without leaving its technical spirit or its main characteristics.
    Examples [0077] The following will describe an experiment performed by the inventors of the present application. In this experiment, using a plurality of steels, (symbol steels A to MMM) having the chemical compositions listed in Table 1 and Table 2, samples of hot-rolled steel sheets were produced having the steel structures
    Petition 870170016959, of 03/15/2017, p. 25/53
    23/47 listed in Table 3 to Table 5, and their mechanical characteristics were investigated. The balance of each of the steels is Fe and impurities. In addition, the bainite area ratio in Table 3 to Table 6 is the bainite area ratio composed of a bainitic ferrite aggregate whose average grain disorientation is 0.4 ° or more at 3 ° or less. The coating layer of sample No. 29 is a hot dip coating layer.
    [0078] The ferrite area ratio was specified by observing the cross section parallel to the rolling direction in a region between 3/8 and 5/8 of the thickness of the hot-rolled steel sheet from the surface at a magnification of 200 times to 500 times using an optical microscope. The bainite area ratio composed of the bainitic ferrite aggregate whose average grain disorientation is 0.4 ° or more to 3 ° or less has been specified by measuring the crystal directions of a plurality of points in the cross section parallel to the direction of rolling in the region between 3/8 and 5/8 the thickness of the hot-rolled steel sheet from the surface by the EBSD method. Each area ratio of perlite, martensite and austenite retained was specified by observing the cross section parallel to the rolling direction in the region between 3/8 and 5/8 of the thickness of the hot-rolled steel sheet from the surface to an enlargement 200 to 500 times using an optical microscope.
    [0079] Then, the tensile test and the hole expansion test of each hot-rolled steel sheet were performed. The tensile test was performed using a specimen No. 5, which is described in Japan Industrial Standard (JIS) Z 2201, manufactured from each hot-rolled steel sheet according to the method described in Japan Industrial Standard (JIS) Z 2241. The hole expansion test was performed according to a method described in Japan Industrial Standard (JIS) Z 2256. The results of the above are listed
    Petition 870170016959, of 03/15/2017, p. 26/53
    24/47 in Table 3 to Table 5.
    [0080] As listed in Table 3 to Table 5, only in samples within the scope of the present invention, excellent elongation and bore expansion capacity could be obtained, while high strength was obtained. In the evaluation of the mechanical characteristics, it was aimed that the tensile strength was 590 MPa or more, that the product (TS χ λ) of the tensile strength (TS (MPa)) by the bore expansion ratio (λ (%)) was 65000 or more, and that the product (EL χ λ) of the total elongation (EL (%)) by the bore expansion ratio (λ (%)) was 1300 or more. In sample n ° 60, since the steel (symbol F steel) contained excess Mn, the plate fractured and the hot-rolled steel plate was not capable of being produced.
    [0081] Each hot rolled steel sheet was produced as below under a condition listed in Table 6 to Table 9. After melting in a steel converter and continuous rolling were performed, reheating to a heating temperature was performed listed in Table 3 to Table 6, and hot rolling including roughing rolling and 7-pass finishing rolling was performed. The temperature and the cumulative reduction of the final step of the roughing lamination are listed in Table 3 to Table 6. In addition, the final temperature of the lamination and the reduction of the sixth pass and the final temperature of the lamination (T1) and the reduction of the seventh pass (final step) of the finishing lamination are listed in Table 3 to Table 6. The thickness after the hot lamination was 1.2 mm to 5.4 mm. After the time t1 (seconds) has passed since the end of the finishing lamination, the cooling to the temperature T2 listed in Table 3 to Table 6 was performed on an exit table. Then, once the temperature reached temperature T2, air cooling was started. Air cooling time t2 is listed in Table 3 to Table 6. After air cooling for time t2,
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    25/47 cooling was performed to the winding temperature listed in Table 3 to Table 6 at a cooling rate P (° C / s) listed in Table 3 to Table 6, and winding was performed at the winding temperature, from so that a hot rolled coil could be manufactured. Subsequently, two-stage cooling of the first cooling and the second cooling was performed. The first cooling started at the starting temperature listed in Table 3 to Table 6, and ended at the final temperature listed in Table 3 to Table 6. The cooling rate during the first cooling is listed in Table 3 to Table 6. The second cooling started at the beginning temperature listed in Table 3 to Table 6, and ended at 25 ° C. The cooling rate during the second cooling is listed in Table 3 to Table 6. In addition, in the production of the hot-rolled steel plate of sample No. 29, the hot immersion was performed after the end of the second cooling.
    Petition 870170016959, of 03/15/2017, p. 28/53
    Table 1
    Steel symbol Ç Si Mn P s Al N B THE You Nb Mo Ass Ni V Cr Here REM T3 (° C) THE 0.041 0.954 1,250 0.007 0.001 0.0045 0.0036 0.0002 0.0032 0.123 0.036 0.005 0.0010706 B 0.008 0.955 1,260 0.007 0.001 0.0046 0.0038 0.0002 0.0030 0.125 0.037 0.040 0.0009711 Ç 0.210 0.955 1,260 0.007 0.001 0.0046 0.0038 0.0002 0.0030 0.125 0.037 0.040 0.0009657 D 0.040 0.007 1,250 0.007 0.001 0.0045 0.0036 0.0002 0.0032 0.123 0.036 0.005 0.0010706 AND 0.041 0.954 0.001 0.007 0.001 0.0045 0.0036 0.0002 0.0032 0.123 0.036 0.005 0.0010818 F 0.041 0.954 6,900 0.007 0.001 0.0045 0.0036 0.0002 0.0032 0.123 0.036 0.005 0.0010198 G 0.040 0.954 1,250 0.500 0.001 0.0045 0.0036 0.0002 0.0032 0.123 0.036 0.005 0.0010706 H 0.041 0.954 1,250 0.007 0.080 0.0450 0.0036 0.0002 0.0032 0.123 0.036 0.005 0.0010706 I 0.039 0.954 1,250 0.007 0.001 0.0005 0.0036 0.0002 0.0032 0.123 0.036 0.005 0.0010707 J 0.041 0.954 1,250 0.007 0.001 0.1000 0.0036 0.0002 0.0032 0.123 0.036 0.005 0.0010706 K 0.042 0.954 1,250 0.007 0.001 0.0045 0.0800 0.0002 0.0032 0.123 0.036 0.005 0.0010706 L 0.041 0.954 1,250 0.007 0.001 0.0045 0.0036 0.0002 0.1400 0.123 0.036 0.005 0.0010706 M 0.042 0.954 1,250 0.007 0.001 0.0045 0.0036 0.0002 0.0032 0.001 0.036 0.005 0.0010706 N 0.040 0.954 1,250 0.007 0.001 0.0045 0.0036 0.0002 0.0032 0.123 0.001 0.005 0.0010706 THE 0.039 0.954 1,250 0.007 0.001 0.0045 0.0036 0.0002 0.0032 0.123 0.036 0.0001 0.0010707 P 0.038 0.954 1,250 0.007 0.001 0.0045 0.0036 0.0001 0.0032 0.123 0.036 0.005 0.0010707 Q 0.041 0.954 1,250 0.007 0.001 0.0045 0.0036 0.0002 0.0032 0.123 0.036 0.005 0.0001706 R 0.085 0.954 1,250 0.007 0.001 0.0045 0.0036 0.0002 0.0032 0.123 0.036 0.005 0.0010694 s 0.065 0.954 1,250 0.007 0.001 0.0045 0.0036 0.0002 0.0032 0.123 0.036 0.005 0.0010700 T 0.025 0.954 1,250 0.007 0.001 0.0045 0.0036 0.0002 0.0032 0.123 0.036 0.005 0.0010710 U 0.039 1,500 1,250 0.007 0.001 0.0045 0.0036 0.0002 0.0032 0.123 0.036 0.005 0.0010707 V 0.040 0.800 1,250 0.007 0.001 0.0045 0.0036 0.0002 0.0032 0.123 0.036 0.005 0.0010706 W 0.041 0.050 1,250 0.007 0.001 0.0045 0.0036 0.0002 0.0032 0.123 0.036 0.005 0.0010706 X 0.039 0.954 2,300 0.007 0.001 0.0045 0.0036 0.0002 0.0032 0.123 0.036 0.005 0.0010612 Y 0.039 0.954 1,000 0.007 0.001 0.0045 0.0036 0.0002 0.0032 0.123 0.036 0.005 0.0010729 Z 0.041 0.954 0.700 0.007 0.001 0.0045 0.0036 0.0002 0.0032 0.123 0.036 0.005 0.0010812 AA 0.041 0.954 1,250 0.080 0.001 0.0045 706 BB 0.040 0.954 1,250 0.008 0.001 0.0045 0.00360.0032707
    26/47
    Petition 870170016959, of 03/15/2017, p. 29/53
    Table 1 (continued)
    Steel symbol Ç Si Mn P s Al N B THE You Nb Mo Ass Ni V Cr Here REM T3 (° C) CC 0.041 0.954 1,250 0.004 0.001 0.0045 0.00360.0032 0.0010706 DD 0.039 0.954 1,250 0.007 0.010 0.0045 0.0036 0.0002 0.0032 0.123 0.036 0.005 707 AND IS 0.042 0.954 1,250 0.007 0.002 0.0045 0.0036 0.0002 0.0032 0.123 0.036 0.005 0.0010 0.0010 706
    27/47
    Petition 870170016959, of 03/15/2017, p. 30/53
    Table 2
    Steel symbol Ç Si Mn P s Al N B THE You Nb Mo Ass Ni V Cr Here REM T3(° C) FF 0.041 0.954 1,250 0.007 0.001 0.0045 0.0036 0.0002 0.0032 0.123 0.036 0.005 0.0010706 GG 0.041 0.954 1,250 0.007 0.001 0.0045 0.0100 0.0002 0.0032 0.123 0.036 0.005 0.0010706 HH 0.039 0.954 1,250 0.007 0.001 0.0045 0.0040 0.0002 0.0032 0.123 0.036 0.005 0.0010707 II 0.040 0.954 1,250 0.007 0.001 0.0045 0.0010 0.0002 0.0032 0.123 0.036 0.005 0.0010706 JJ 0.041 0.954 1,250 0.007 0.001 0.0045 0.0036 0.0002 0.0100 0.123 0.036 0.005 0.0010706 KK 0.039 0.954 1,250 0.007 0.001 0.0045 0.0036 0.0002 0.0040 0.123 0.036 0.005 0.0010707 LL 0.039 0.954 1,250 0.500 0.001 0.0045 0.0036 0.0002 0.0020 0.123 0.036 0.005 0.0010707 MM 0.041 0.954 1,250 0.007 0.001 0.0080 0.0036 0.0002 0.0032 0.123 0.036 0.005 0.0010706 NN 0.041 0.954 1,250 0.007 0.001 0.0050 0.0036 0.0002 0.0032 0.123 0.036 0.005 0.0010706 OO 0.040 0.954 1,250 0.007 0.001 0.0020 0.0036 0.0002 0.0032 0.123 0.036 0.005 0.0010706 PP 0.041 0.954 1,250 0.007 0.001 0.0045 0.0036 0.0002 0.0032 0.144 0.036 0.005 0.0010706 QQ 0.390 0.954 1,250 0.007 0.001 0.0045 0.0036 0.0002 0.0032 0.110 0.036 0.005 0.0010707 RR 0.041 0.954 1,250 0.007 0.001 0.0045 0.0036 0.0002 0.0032 0.050 0.036 0.005 0.0010706 SS 0.041 0.954 1,250 0.007 0.001 0.0045 0.0036 0.0002 0.0032 0.123 0.144 0.005 0.0010706 TT 0.040 0.954 1,250 0.007 0.001 0.0045 0.0036 0.0002 0.0032 0.123 0.109 0.005 0.0010706 UU 0.041 0.954 1,250 0.007 0.001 0.0045 0.0036 0.0002 0.0032 0.123 0.054 0.005 0.0010706 VV 0.039 0.954 1,250 0.007 0.001 0.0045 0.0036 0.0002 0.0032 0.123 0.036 0.139 0.0010695 WW 0.041 0.954 1,250 0.007 0.001 0.0045 0.0036 0.0002 0.0032 0.123 0.036 0.106 0.0010698 XX 0.042 0.954 1,250 0.007 0.001 0.0045 0.0036 0.0002 0.0032 0.123 0.036 0.049 0.0010702 YY 0.041 0.954 1,250 0.007 0.001 0.0045 0.0036 0.0002 0.0032 0.123 0.036 0.005 0.1450.0010706 ZZ 0.042 0.954 1,250 0.007 0.001 0.0045 0.0036 0.0002 0.0032 0.123 0.036 0.005 0.1050.0010706 AAA 0.040 0.954 1,250 0.007 0.001 0.0045 0.0036 0.0002 0.0032 0.123 0.036 0.005 0.0450.0010706 BBB 0.039 0.954 1,250 0.007 0.001 0.0045 0.0036 0.0002 0.0032 0.123 0.036 0.005 0.143 0.0010697 CCC 0.038 0.954 1,250 0.007 0.001 0.0045 0.0036 0.0002 0.0032 0.123 0.036 0.005 0.102 0.0010700 DDD 0.041 0.954 1,250 0.007 0.001 0.0045 0.0036 0.0002 0.0032 0.123 0.036 0.005 0.034 0.0010704 EEE 0.041 0.954 1,250 0.007 0.001 0.0045 0.0036 0.0060 0.0032 0.123 0.036 0.005 0.0010706 FFF 0.041 0.954 1,250 0.080 0.001 0.0045 0.0036 0.0003 0.0032 0.123 0.036 0.005 0.0010706 GGG 0.039 0.954 1,250 0.008 0.001 0.0045 0.0036 0.0001 0.0032 0.123 0.036 0.005 0.0010707
    28/47
    Petition 870170016959, of 03/15/2017, p. 31/53
    Table 2
    Steel symbol Ç Si Mn P s Al N B THE You Nb Mo Ass Ni V Cr Here REM T3(° C) HHH 0.041 0.954 1,250 0.004 0.001 0.0045 0.0036 0.0002 0.0032 0.123 0.036 0.005 0.900 0.0010706 III 0.041 0.954 1,250 0.007 0.001 0.0045 0.0036 0.0002 0.0032 0.123 0.036 0.005 0.080 0.0010706 JJJ 0.040 0.954 1,250 0.007 0.001 0.0045 0.0036 0.0002 0.0032 0.123 0.036 0.005 0.040 0.0010706 KKK 0.041 0.954 1,250 0.007 0.001 0.0045 0.0036 0.0002 0.0032 0.123 0.036 0.0050.350 0.0010693 LLL 0.039 0.954 1,250 0.007 0.001 0.0045 0.0036 0.0002 0.0032 0.123 0.036 0.0050.090 0.0010703 MMM 0.041 0.954 1,250 0.007 0.001 0.0045 0.0036 0.0002 0.0032 0.123 0.036 0.0050.020 0.0010705
    29/47
    Petition 870170016959, of 03/15/2017, p. 32/53
    Table 3
    Sample No. Steel symbol Ferrite area ratio (%) Bainite area ratio (%) Area ratio of martensite (%) Perlite area ratio (%) Area ratio of retained austenite (%) 1 THE 32 66.6 0.10 1.00 0.10 2 THE 20 78.9 0.10 0.90 0.10 3 THE 48 50.9 0.10 1.10 0.10 4 THE 39 59.9 0.10 0.90 0.10 5 THE 21 77.8 0.10 1.00 0.10 6 THE 48 50.6 0.10 1.10 0.10 7 THE 39 60.0 0.10 0.90 0.10 8 THE 39 60.1 0.10 1.00 0.10 9 THE 32 66.7 0.10 1.00 0.10 10 THE 21 77.6 0.10 0.90 0.10 11 THE 21 77.7 0.10 1.10 0.10 12 THE 32 66.8 0.10 1.10 0.10 13 THE 39 60.1 0.10 1.00 0.10 14 THE 39 60.2 0.10 1.10 0.10 15 THE 21 77.7 0.10 1.00 0.10 16 THE 21 78.0 0.10 0.90 0.10 17 THE 29 69.9 0.10 1.00 0.10 18 THE 32 66.8 0.10 0.90 0.10 19 THE 21 77.9 0.10 1.00 0.10 20 THE 21 77.8 0.10 1.00 0.10 21 THE 32 66.5 0.10 1.10 0.10 22 THE 39 59.8 0.10 1.10 0.10 23 THE 39 59.8 0.10 1.00 0.10 24 THE 32 66.9 0.10 0.90 0.10 25 THE 21 77.8 0.10 0.90 0.10 26 THE 32 63.6 3.20 1.00 0.10 27 THE 32 66.7 0.10 1.10 0.10 28 THE 32 66.4 0.10 1.10 0.10 29 THE 32 66.4 0.10 1.00 0.10 30 THE 4 94.8 0.10 0.90 0.10 31 THE 71 27.9 0.10 0.90 0.10
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    31/47
    32 THE 71 28.0 0.10 1.00 0.10 33 THE 4 94.7 0.10 0.90 0.10 34 THE 4 94.6 0.10 1.10 0.10 35 THE 4 94.4 0.10 1.10 0.10 36 THE 4 94.9 0.10 1.00 0.10 37 THE 4 94.6 0.10 1.00 0.10 38 THE 71 27.7 0.10 0.90 0.10 39 THE 71 27.6 0.10 0.90 0.10
    Table 3 (Continued)
    Total area ratio of martensite, perlite and austenite retained (%) TS (MPa) EL (%) λ (%) TS x λ MPa.%) EL x λ (%.%) Coating layer 1.20 810.00 18 85 68850 1530 WITHOUT 1.10 811.00 17 101 81991 1717 WITHOUT 1.30 815.00 18 85 69275 1530 WITHOUT 1.10 798.00 19 81 64638 1539 WITHOUT 1.20 799.00 16 102 81498 1632 WITHOUT 1.30 810.00 18 84 68040 1512 WITHOUT 1.10 811.00 19 81 65691 1539 WITHOUT 1.20 809.00 18 82 66338 1476 WITHOUT 1.20 804.00 18 86 69144 1548 WITHOUT 1.10 812.00 16 102 82824 1632 WITHOUT 1.30 805.00 16 103 82915 1648 WITHOUT 1.30 800.00 18 87 69600 1566 WITHOUT 1.20 801.00 19 82 65682 1558 WITHOUT 1.30 809.00 19 r »a 65529 1539 WITHOUT 1.20 799.00 1867915 1530 WITHOUT 1.10 794.00 16 1 0 1 80194 1616 WITHOUT 1.20 798.00 19 81 64638 1539 WITHOUT 1.10 810.00 18 85 68850 1530 WITHOUT 1.20 811.00 16 101 81911 1616 WITHOUT 1.20 811.00 16 102 82722 1632 WITHOUT 1.30 812.00 18 85 69020 1530 WITHOUT 1.30 810.00 19 81 65610 1539 WITHOUT
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    Petition 870170016959, of 03/15/2017, p. 34/53
    32/47
    Table 3 (Continued)
    1.20 810.00 19 82 66420 1558 WITHOUT 1.10 809.00 18 85 68765 1530 WITHOUT 1.10 806.00 16 100 80600 1600 WITHOUT 4.30 830.00 18 80 66400 1440 WITHOUT 1.30 812.00 18 84 68208 1512 WITHOUT 1.30 810.00 18 85 68850 1530 WITHOUT 1.20 810.00 18 86 69660 1548 WITH 1.10 809.00 12 65 52585 780 WITHOUT 1.10 775.00 20 45 34875 900 WITHOUT 1.20 769.00 20 46 35374 920 WITHOUT 1.10 841.00 12 65 54665 780 WITHOUT 1.30 838.00 12 66 55308 792 WITHOUT 1.30 840.00 12 65 54600 780 WITHOUT 1.20 839.00 12 66 55374 792 WITHOUT 1.20 840.00 12 65 54600 780 WITHOUT 1.10 771.00 20 45 34695 900 WITHOUT 1.10 772.00 20 44 33968 880 WITHOUT
    Petition 870170016959, of 03/15/2017, p. 35/53
    Table 4
    Sample No. Steel symbol Ferrite area ratio (%) Bainite area ratio (%) Area ratio of martensite (%) Perlite area ratio (%) Area ratio of retained austenite (%) 40 THE 71 27.9 0.10 1.00 0.10 41 THE 71 27.9 0.10 1.00 0.10 42 THE 71 27.7 0.10 0.90 0.10 43 THE 4 94.7 0.10 1.10 0.10 44 THE 71 27.7 0.10 1.00 0.10 45 THE 4 94.8 0.10 0.90 0.10 46 THE 32 36.6 0.10 31.10 0.10 47 THE 30 41.2 0.10 28.90 0.10 48 THE 32 36.2 0.10 31.50 0.10 49 THE 71 27.8 0.10 1.10 0.10 50 THE 32 39.6 27.20 1.00 0.10 51 THE 32 37.0 0.10 30.90 0.10 52 THE 32 40.2 26.90 1.00 0.10 53 THE 32 43.6 20.90 0.90 2.90 54 THE 32 36.4 0.10 31.40 0.10 55 THE 32 39.8 27.00 1.00 0.10 56 B 32 66.4 0.10 1.00 0.10 57 Ç 32 40.0 27.00 1.00 0.10 58 D 32 37.0 0.10 31.00 0.11 59 AND 32 67.0 0.10 1.00 0.10 60 F61 G 32 66.7 0.10 1.00 0.10 62 H 32 67.0 0.10 0.90 0.10 63 I 32 67.1 0.10 0.90 0.10 64 J 32 67.1 0.10 1.00 0.10 65 K 32 66.7 0.10 1.10 0.10 66 L 32 66.6 0.10 1.10 0.10 67 M 32 66.4 0.10 1.00 0.10 68 N 32 67.0 0.10 0.90 0.10
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    69 THE 32 67.0 0.10 0.90 0.10 70 P 32 67.0 0.10 1.00 0.10 71 Q 32 66.8 0.10 0.90 0.10 72 R 20 78.8 0.10 1.10 0.10 73 s 35 63.9 0.10 1.10 0.10 74 T 45 53.8 0.10 1.00 0.10 75 U 32 66.7 0.10 1.00 0.10 76 V 32 67.0 0.10 0.90 0.10 77 W 32 67.1 0.10 0.90 0.10 78 X 32 67.1 0.10 1.00 0.10
    Table 4 (Continued)
    Total area ratio of martensite, perlite and austenite retained (%) TS (MPa) EL (%) λ (%) TS x λ MPa.%) EL x λ (%.%) Coating layer 1.20 768.00 20 45 34560 900 WITHOUT 1.20 770.00 20 44 33880 880 WITHOUT 1.10 771.00 20 45 34695 900 WITHOUT 1.30 838.00 12 65 54470 780 WITHOUT 1.20 771.00 20 43 33153 860 WITHOUT 1.10 839.00 12 64 53696 768 WITHOUT 31.30 768.00 18 45 34560 810 WITHOUT 29.10 770.00 18 45 34650 810 WITHOUT 31.70 768.00 18 45 34560 810 WITHOUT 1.30 770.00 20 44 33880 880 WITHOUT 28.30 838.00 12 55 46090 660 WITHOUT 31.10 773.00 18 45 34785 810 WITHOUT 28.00 837.00 12 56 46872 672 WITHOUT 24.70 773.00 18 44 34012 792 WITHOUT 31.60 771.00 18 46 35466 828 WITHOUT 28.10 837.00 12 57 47709 684 WITHOUT 1.20 342.00 18 45 15390 810 WITHOUT 28.10 840.00 12 57 47880 684 WITHOUT
    34/47
    Petition 870170016959, of 03/15/2017, p. 37/53
    31.21 772.00 18 44 33968 792 WITHOUT 1.20 341.00 18 45 15345 810 WITHOUT 1.20 851.00 11 37 31487 407 WITHOUT 1.10 811.00 18 29 23519 522 WITHOUT 1.10 810.00 6 85 68850 510 WITHOUT 1.20 809.00 6 86 69574 516 WITHOUT 1.30 851.00 18 14 11914 252 WITHOUT 1.30 811.00 18 15 12165 270 WITHOUT 1.20 816.00 18 86 15570 810 WITHOUT 1.10 816.00 18 86 15916 828 WITHOUT 1.10 811.00 18 87 15345 810 WITHOUT 1.20 812.00 18 87 15732 828 WITHOUT 1.10 811.00 18 87 17031 378 WITHOUT 1.30 1030.00 28 75 77250 2100 WITHOUT 1.30 820.00 18 85 69700 1530 WITHOUT 1.20 610.00 18 120 73200 2160 WITHOUT 1.20 851.00 18 85 72335 1530 WITHOUT 1.10 830.00 18 86 71380 1548 WITHOUT 1.10 790.00 18 86 67940 1548 WITHOUT 1.20 852.00 18 85 72420 1530 WITHOUT
    35/47
    Table 5
    Sample No.79 Steel symbolY Ferrite area ratio (%) 32.0 Bainite area ratio (%) 66.8 Martensite area ratio (%) 0.10 Perlite area ratio (%) 1.00 Area ratio of retained austenite (%) 0.10 80 Z 32.0 66.8 0.10 0.90 0.10 81 AA 32.0 66.3 0.10 1.10 0.10 82 BB 32.0 66.9 0.10 1.00 0.10 83 CC 32.0 67.0 0.10 0.90 0.10
    Petition 870170016959, of 03/15/2017, p. 38/53
    Table 5 (Continued)
    84 DD 32.0 67.0 0.10 1.00 0.10 85 AND IS 32.0 66.6 0.10 1.00 0.10 86 FF 32.0 67.1 0.10 0.90 0.10 87 GG 32.0 67.1 0.10 1.00 0.10 88 HH 32.0 66.8 0.10 1.00 0.10 89 II 32.0 66.8 0.10 0.90 0.10 90 JJ 32.0 66.3 0.10 1.10 0.10 91 KK 32.0 66.8 0.10 1.10 0.10 92 LL 32.0 66.9 0.10 1.00 0.10 93 MM 32.0 66.5 0.10 1.10 0.10 94 NN 32.0 66.6 0.10 1.00 0.10 95 OO 32.0 66.8 0.10 0.90 0.10 96 PP 32.0 66.7 0.10 1.00 0.10 97 QQ 32.0 61.9 5.10 0.90 0.10 98 RR 32.0 66.9 0.10 1.00 0.10 99 SS 32.0 67.0 0.10 1.00 0.10 100 TT 32.0 67.0 0.10 1.10 0.10 101 UU 32.0 66.7 0.10 1.10 0.10 102 VV 32.0 66.7 0.10 1.00 0.10 103 WW 32.0 66.5 0.10 0.90 0.10 104 XX 32.0 67.0 0.10 0.90 0.10 105 YY 32.0 66.9 0.10 1.00 0.10 106 ZZ 32.0 67.0 0.10 1.00 0.10 107 AAA 32.0 66.6 0.10 1.00 0.10 108 BBB 32.0 67.0 0.10 1.00 0.10 109 CCC 32.0 67.0 0.10 1.10 0.10 110 DDD 32.0 66.8 0.10 1.00 0.10 111 EEE 32.0 66.8 0.10 0.90 0.10 112 FFF 32.0 66.4 0.10 1.00 0.10 113 GGG 32.0 67.0 0.10 0.90 0.10
    36/47
    Petition 870170016959, of 03/15/2017, p. 39/53
    Table 5 (Continued)
    114 HHH 32.0 66.9 0.10 1.00 0.10 115 III 32.0 66.7 0.10 1.00 0.10 116 JJJ 32.0 66.7 0.10 1.10 0.10 117 KKK 32.0 66.5 0.10 1.10 0.10 118 LLL 32.1 66.7 0.10 1.00 0.09 119 MMM 31.8 67.1 0.09 0.90 0.09
    Table 5 (Continued)
    Total area ratio of martensite, perlite and austenite retained (%) TS (MPa) EL (%) λ(%) TS x λ(MPa.%) EL x λ (%.%) Coating layer 1.20 830.00 18 86 71380 1548 WITHOUT 1.10 792.00 18 85 67320 1530 WITHOUT 1.30 813.00 18 85 69105 1530 WITHOUT 1.20 810.00 19 96 77760 1824 WITHOUT 1.20 815.00 21 101 82315 2121 WITHOUT 1.20 806.00 18 85 68510 1530 WITHOUT 1.20 802.00 19 95 76190 1805 WITHOUT 1.10 814.00 21 100 81400 2100 WITHOUT 1.20 815.00 18 85 69275 1530 WITHOUT 1.20 816.00 19 95 77520 1805 WITHOUT 1.10 812.00 21 102 82824 2142 WITHOUT 1.30 811.00 18 85 68935 1530 WITHOUT 1.30 812.00 19 95 77140 1805 WITHOUT 1.20 813.00 21 45 36585 945 WITHOUT 1.30 813.00 18 85 69105 1530 WITHOUT 1.20 815.00 19 95 77425 1805 WITHOUT 1.10 809.00 21 100 80900 2100 WITHOUT 1.20 847.00 18 85 71995 1530 WITHOUT 1.10 829.00 18 44 36476 792 WITHOUT 1.20 811.00 17 85 68935 1445 WITHOUT
    37/47
    Petition 870170016959, of 03/15/2017, p. 40/53
    1.20 853.00 18 86 73358 1548 WITHOUT 1.30 834.00 18 85 70890 1530 WITHOUT 1.30 814.00 18 85 69190 1530 WITHOUT 1.20 855.00 17 86 73530 1462 WITHOUT 1.10 828.00 18 86 71208 1548 WITHOUT 1.10 809.00 17 86 69574 1462 WITHOUT 1.20 842.00 18 85 71570 1530 WITHOUT 1.20 825.00 18 86 70950 1548 WITHOUT 1.20 809.00 17 86 69574 1462 WITHOUT 1.20 841.00 18 85 72326 1548 WITHOUT 1.30 827.00 17 85 70295 1445 WITHOUT 1.20 809.00 17 85 68765 1445 WITHOUT 1.10 855.00 17 86 73530 1462 WITHOUT 1.20 829.00 18 86 71294 1548 WITHOUT 1.10 809.00 18 85 68765 1530 WITHOUT 1.20 851.00 18 85 72335 1530 WITHOUT 1.20 832.00 17 86 71552 1462 WITHOUT 1.30 809.00 17 86 69574 1462 WITHOUT 1.30 841.00 18 85 71485 1530 WITHOUT 1.19 829.00 17 86 71284 1462 WITHOUT 1.08 808.00 18 85 59488 1548 WITHOUT
    38/47
    Petition 870170016959, of 03/15/2017, p. 41/53
    Table 6
    Sample No. Steel symbol Reheat Blade-dog thinning Blade-dog in finishing Time elapsed until coolingt1 (s) Cooling on air Final temperature(° C) Reductioncumulative(%) Final temperatureof the 6th pass(° C) Reduction of6th pass(%) Final temperature of the 7th pass (° C) Reduction of7th pass(%) Start temperatureT2 (° C) Time(s ) Temperature (° C) 1 THE 1200 1100 55 950 15 900 8 2 670 4 2 THE 1206 1105 54 1100 14 890 7 2 677 3 3 THE 1203 1104 54 960 13 908 6 2 664 6 4 THE 1201 1102 55 890 14 904 5 2 665 5 5 THE 1200 1107 56 951 30 902 7 2 667 4 6 THE 1206 1102 54 951 17 906 7 2 668 6 7 THE 1209 1108 56 954 11 895 8 2 662 3 8 THE 1203 1109 55 955 16 1020 6 2 669 4 9 THE 1205 1107 55 951 15 910 6 2 671 5 10 THE 1203 1105 55 956 14 860 5 2 678 3 11 THE 1204 1103 55 957 15 890 9 2 675 6 12 THE 1203 1102 55 953 15 908 7 2 670 5 13 THE 1206 1105 54 954 14 905 4 2 671 4 14 THE 1206 1109 55 955 16 896 8 2 730 6 15 THE 1208 1102 56 957 13 897 6 2 660 3 16 THE 1209 1104 54 953 12 901 5 2 620 4 17 THE 1203 1102 53 951 15 904 7 2 664 9 18 THE 1204 1103 56 952 16 903 5 2 665 5 19 THE 1203 1106 57 953 15 896 6 2 667 2 20 THE 1201 1109 54 958 14 895 7 2 668 4 21 THE 1200 1102 55 946 13 906 6 2 662 6 22 THE 1206 1103 54 956 12 903 5 2 669 5 23 THE 1209 1102 57 950 14 902 8 2 671 7 24 THE 1203 1104 54 953 15 907 8 2 678 6 25 THE 1203 1105 53 952 16 901 8 2 675 4 26 THE 1206 1104 56 954 15 904 6 2 671 5 27 THE 1206 1108 57 951 14 906 7 2 679 6 28 THE 1208 1102 54 952 14 905 5 2 668 4 29 THE 1209 1103 56 954 13 904 8 2 665 5
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    Petition 870170016959, of 03/15/2017, p. 42/53
    Table 6 continued
    Right side of the formula1 Resfr. after theair-cooled cooling First cooling T3 - 300(° C) Second cooling Start temperature(° C) End temperature(° C) Cooling rate(° C / m) Start temperature(° C) Cooling rate(° C / m) Cooling rateP (° C / s) Temperature (° C) 18 19 606 596 412 0.10 406 391 0.02 19 25 601 591 409 0.12 406 389 0.03 16 24 605 595 409 0.09 406 389 0.02 17 21 501 591 413 0.08 406 390 0.03 18 19 599 589 411 0.09 406 387 0.03 16 18 598 588 409 0.11 406 391 0.02 20 21 603 593 412 0.12 406 390 0.03 18 28 601 591 413 0.09 406 387 0.03 17 19 598 588 412 0.08 406 386 0.02 19 21 603 593 411 0.12 406 384 0.02 16 17 606 595 410 0.11 406 386 0.02 17 21 601 591 413 0.10 406 389 0.03 18 18 600 590 408 0.09 406 381 0.03 13 19 599 589 409 0.08 406 381 0.02 20 21 598 588 410 0.11 406 389 0.03 21 23 602 592 412 0.10 406 391 0.02 14 28 601 591 409 0.12 406 390 0.03 17 19 600 590 411 0.09 406 381 0.02 23 25 606 596 410 0.09 406 382 0.03 18 21 640 630 409 0.08 406 383 0.02 16 23 590 580 413 0.07 406 390 0.03 17 19 450 440 410 0.09 406 387 0.02 15 21 601 591 409 0.13 406 386 0.02 16 18 605 595 412 0.09 406 390 0.03 18 19 601 591 412 0.04 406 388 0.03 17 21 599 589 413 0.08 406 387 0.04 16 19 598 588 412 0.09 406 385 0.02 18 19 603 593 411 0.11 406 384 0.01 17 19 601 591 410 0.12 406 386 0.03
    40/47
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    Table 7
    Reheat Lamination thinningLamination in finishing Past time Sample SymbolTemperature Reduction Final temperature Reduction of Final temperature Reduction of until the n ° of steel Temperature Final cumulative of the 6th pass 6th pass of the 7th pass 7th pass cooling (° C) (° C) (%) (° C) (%) (° C) (%) t1 (s) 30 THE 1203 1290 57 951 15 906 6 2 31 THE 1204 1020 54 950 16 908 7 2 32 THE 1203 1109 78 950 14 902 5 2 33 THE 1201 1107 31 954 15 901 6 2 34 THE 1200 1105 54 1190 13 902 7 2 35 THE 1203 1103 54 820 12 905 8 2 36 THE 1204 1102 55 954 58 904 8 2 37 THE 1203 1105 56 955 6 901 6 2 38 THE 1206 1109 54 951 16 1080 7 2 39 THE 1206 1102 56 956 15 810 6 2 40 THE 1200 1104 55 957 14 905 15 2 41 THE 1206 1102 55 953 15 904 2 2 42 THE 1209 1103 55 954 15 906 6 2 43 THE 1203 1106 55 955 14 908 5 2 44 THE 1203 1109 55 957 16 902 7 2 45 THE 1206 1107 54 953 13 901 7 2 46 THE 1206 1105 55 951 12 906 8 2 47 THE 1206 1105 55 951 12 906 8 2 48 THE 1206 1105 55 951 12 906 8 2 49 THE 1200 1103 56 950 15 903 6 2 50 THE 1200 1102 54 951 16 902 6 2 51 THE 1210 1105 53 956 15 907 7 2 52 THE 1209 1103 56 957 14 901 5 2 53 THE 1205 1102 57 953 13 904 6 2 54 THE 1202 1106 54 954 12 906 7 2 55 THE 1203 1109 55 955 14 905 8 2 56 B 1200 1102 54 957 15 904 8 2 57 Ç 1200 1104 57 950 15 906 6 2 58 D 1202 1105 54 955 13 908 7 2
    41/47
    Petition 870170016959, of 03/15/2017, p. 44/53
    Table 7 Continuation
    Cooling on air SideRight Resfr. after theair-cooled cooling First cooling T3 - 300 Second cooling Temperatu- Time Temperatu- Temperatu- Rate of Temperature Rate of froggives frog frog from startformula Rate of Temperatu- from start ending coolingfrom start cooling cool. frog T2 (° C) (s) 1 P (° C / s) (° C) (° C) (° C) (° C / m) (° C) (° C) (° C / m) 669 6 16 21 598 588 413 0.09 406 384 0.03 661 4 19 20 603 593 408 0.08 406 386 0.02 772 5 13 18 605 595 409 0.12 406 381 0.03 670 6 16 21 601 591 410 0.11 406 389 0.03 670 4 18 22 600 580 412 0.10 406 391 0.02 667 6 16 20 599 589 409 0.09 406 390 0.02 668 5 17 19 598 588 409 0.08 406 381 0.02 662 7 16 18 602 592 413 0.11 406 382 0.03 669 6 15 17 601 591 411 0.10 406 383 0.03 671 4 19 21 600 590 409 0.10 406 390 0.02 678 5 16 18 606 596 412 0.10 406 387 0.03 675 6 16 19 606 596 412 0.10 406 386 0.02 810 5 17 21 606 596 413 0.08 406 390 0.03 540 7 15 18 520 510 412 0.12 406 388 0.02 668 19 12 19 606 596 411 0.11 406 387 0.03 665 0.4 37.4 17 606 596 410 0.10 406 391 0.02 669 6 16 6 606 596 412 0.11 406 391 0.03 669 5 17 4 606 596 412 0.11 406 391 0.03 669 6 16 2 606 596 412 0.11 406 391 0.03 661 4 19 20 710 700 412 0.12 406 391 0.03 670 5 17 18 310 300 397 0.09 406 390 0.02 668 6 16 19 606 605 410 0.08 406 388 0.03 665 4 18 21 606 596 474 0.10 406 387 0.02 669 6 16 23 606 596 412 2.50 406 391 0.03 661 5 17 28 606 596 412 0.10 406 420 0.03 670 7 15 17 606 596 413 0.10 406 391 0.16 670 6 5 18 611 601 412 0.09 411 396 0.02 670 4 86 90 557 547 412 0.08 357 342 0.03 670 4 18 21 606 596 412 0.11 406 391 0.02
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    Table 8
    Sample Symbol Reheat Lamination thinning Lamination in finishing Time passed until Temperature Reduction Final temperature Reduction of Final temperature Reduction of n ° of steel Temperature Final cumulative (%) of the 6th pass 6th pass of the 7th pass 7th pass cooling (° C) (° C) (° C) (%) (° C) (%) t1 (s) 59 AND 1203 1102 53 950 12 900 6 2 60 F 61 G 1200 1103 53 955 16 890 8 2 62 H 1200 1106 56 951 15 906 6 2 63 I 1210 1109 57 956 14 905 5 2 64 J 1209 1107 54 957 15 896 7 2 65 K 1205 1105 55 953 15 897 7 2 66 L 1202 1103 55 954 14 901 8 2 67 M 1203 1102 55 955 16 904 6 2 68 N 1201 1105 55 957 13 903 6 2 69 THE 1202 1103 55 953 12 896 7 2 70 P 1206 1102 55 951 15 895 5 2 71 Q 1209 1106 54 950 16 906 6 2 72 R 1208 1109 54 951 15 903 7 2 73 s 1205 1102 55 956 14 902 8 2 74 T 1202 1104 56 957 13 907 8 2 75 U 1204 1105 54 953 12 901 6 2 76 V 1204 1102 56 954 14 904 7 2 77 W 1207 1103 55 955 15 906 8 2 78 X 1210 1102 55 957 16 905 6 2 79 Y 1202 1106 55 950 15 904 5 2 80 Z 1209 1102 55 955 14 906 7 2 81 AA 1204 1103 55 950 14 908 5 2 82 BB 1205 1102 54 957 13 902 6 2 83 CC 1203 1104 55 953 15 901 7 2 84 DD 1201 1105 56 954 16 902 6 2 85 AND IS 1207 1104 54 955 14 905 5 2 86 FF 1206 1108 53 957 15 904 8 2 87 GG 1205 1102 56 953 13 901 8 2
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    Petition 870170016959, of 03/15/2017, p. 46/53
    Table 8 continued
    Cooling on air Right side Resfr. After air cooling Cooling First cooling T3 - 300 Second cooling Temperature Time Temperature Temperature Rate of Temperature Rate of from startof the formula Rate of Temperatu- from start ending coolingfrom start cooling there cool. frog T2 (° C) (s) 1 P (° C / s) (° C) (° C) (° C) (° C / m) (° C) (° C) (° C / m) 673 5 17 18 685 675 525 0.10 518 503 0.03 661 6 16 17 595 585 409 0.08 395 380 0.03 772 5 13 21 606 596 412 0.09 406 390 0.03 670 4 17 18 607 597 413 0.11 406 387 0.02 670 6 16 19 601 591 412 0.12 407 386 0.03 667 3 20 21 605 595 411 0.09 406 390 0.03 668 4 18 23 601 591 410 0.08 406 388 0.02 662 5 18 28 599 589 413 0.12 406 387 0.02 669 3 19 21 598 588 408 0.11 406 385 0.02 671 6 15 18 603 593 409 0.10 406 384 0.03 678 5 15 21 601 591 410 0.09 407 386 0.03 675 4 18 23 598 588 412 0.08 407 384 0.02 671 6 31 34 603 593 409 0.11 406 386 0.03 679 3 29 33 605 595 411 0.10 394 381 0.02 668 4 12 18 601 591 410 0.10 400 389 0.03 665 5 16 19 600 590 411 0.10 410 395 0.02 669 6 16 21 599 589 413 0.10 407 390 0.03 661 4 19 21 598 588 412 0.08 406 381 0.02 670 6 15 18 602 592 409 0.12 406 382 0.03 668 5 16 17 601 591 412 0.11 312 383 0.03 665 7 16 21 600 590 436 0.10 429 390 0.02 669 6 16 19 606 596 527 0.08 512 387 0.03 661 4 18 21 606 596 412 0.09 406 386 0.02 670 4 18 21 606 596 411 0.11 406 390 0.03 665 5 16 22 606 596 408 0.12 406 388 0.03 667 6 16 20 607 597 409 0.09 407 387 0.03 668 4 18 19 605 595 410 0.08 406 391 0.02 662 5 17 18 601 591 412 0.12 406 391 0.03
    44/47
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    Table 9
    Sample Symbol Reheat Lamination thinning Lamination in finishing Time passed until Temperature Reduction Final temperature Reduction of Final temperature Reduction of n ° of steel Temperature ° C) Final(° C) cumulative (%) 6th pass (° C) 6th pass(%) 7th pass (° C) 7th pass (%) cooling t1 (s) 88 HH 1204 1103 57 951 12 900 8 2 89 II 1203 1109 54 952 15 900 6 2 90 JJ 1201 1102 55 953 15 900 7 2 91 KK 1207 1104 54 958 14 902 5 2 92 LL 1206 1105 57 946 15 905 8 2 93 MM 1204 1102 54 956 15 904 6 2 94 NN 1206 1103 53 950 14 901 7 2 95 OO 1206 1102 56 953 16 902 5 2 96 PP 1203 1106 57 952 13 901 6 2 97 QQ 1201 1102 55 954 12 906 7 2 98 RR 1200 1103 55 951 15 903 8 2 99 SS 1206 1104 55 956 16 902 8 2 100 TT 1209 1105 55 957 15 907 6 2 101 UU 1203 1102 54 953 14 901 7 2 102 VV 1205 1103 57 954 15 904 8 2 103 WW 1203 1102 54 955 15 906 8 2 104 XX 1204 1106 53 957 15 905 5 2 105 YY 1203 1102 56 950 15 904 8 2 106 ZZ 1206 1103 57 955 15 900 6 2 107 AAA 1206 1101 55 950 14 900 7 2 108 BBB 1208 1103 55 957 16 900 5 2 109 CCC 1209 1102 55 953 13 902 6 2 110 DDD 1203 1107 55 954 12 907 7 2 111 EEE 1204 1102 54 855 15 901 8 2 112 FFF 1204 1105 56 957 16 904 8 2 113 GGG 1205 1104 54 953 15 906 6 2 114 HHH 1206 1102 55 951 14 905 7 2 115 III 1208 1107 57 952 15 904 8 2 116 JJJ 1209 1108 54 953 15 900 8 2 117 KKK 1202 1102 53 950 15 900 8 2 118 LLL 1204 1109 52 950 14 900 8 2 119 MMM 1201 1104 55 951 15 903 6 2
    Petition 870170016959, of 03/15/2017, p. 48/53
    45/47
    Table 9 continued
    Cools it down Right side Resfr. after theair-cooled Cooling First cooling T3 - 300 Second cooling Temperatu- Time Temperature Temper- Rate of Temperature Rate of frogstart T2 (° C) (s) of the formula1 Cooling rateP (° C / s) Temperature(° C) ( from start° C) ( tureending C) (‘ coolingC / m) (° 9 ( from start° C) cooling(° C / m) 669 6 15 17 599 589 409 0.11 406 391 0.02 671 4 18 21 598 588 411 0.10 407 390 0.03 678 6 16 18 603 593 410 0.10 406 387 0.03 675 5 16 19 601 591 409 0.09 406 386 0.02 670 7 15 18 598 588 413 0.08 407 390 0.03 671 6 16 18 603 593 408 0.11 407 388 0.02 670 4 18 21 605 595 409 0.10 406 387 0.03 670 5 17 19 601 591 412 0.10 406 391 0.03 670 6 16 18 600 590 412 0.10 406 391 0.03 670 5 16 21 598 589 413 0.10 406 391 0.02 661 7 16 22 598 588 412 0.08 407 392 0.03 670 4 18 20 602 592 412 0.12 406 391 0.02 668 4 18 19 601 591 412 0.11 406 391 0.03 665 4 18 21 600 590 412 0.10 406 391 0.02 669 5 16 17 595 585 412 0.08 406 391 0.03 661 6 16 21 595 585 412 0.09 395 380 0.03 670 4 18 21 598 588 412 0.11 398 383 0.02 665 5 17 19 602 592 412 0.12 402 387 0.03 667 6 17 21 606 596 412 0.09 406 391 0.02 668 4 18 21 606 596 412 0.08 406 391 0.03 662 6 16 19 606 596 412 0.12 406 391 0.03 669 5 16 17 597 587 412 0.10 397 382 0.03 671 7 15 18 600 590 412 0.10 400 385 0.03 678 6 16 18 604 584 412 0.10 404 389 0.03 675 4 16 22 606 596 412 0.10 406 391 0.03 670 5 16 19 605 595 412 0.08 406 391 0.03 671 6 16 18 601 581 412 0.12 407 367 0.02 670 5 17 20 599 589 412 0.11 406 386 0.03 670 7 15 21 598 588 412 0.09 406 390 0.02 670 4 18 21 603 593 411 0.08 406 388 0.03 670 4 17 19 601 591 408 0.11 393 378 0.02 671 5 17 18 598 588 409 0.10 403 388 0.03
    Petition 870170016959, of 03/15/2017, p. 49/53
    46/47
    47/47
    Industrial applicability [0082] The present invention can be used in an industry related to a hot-rolled steel plate used for an underside of an automobile chassis, for example.
    权利要求:
    Claims (3)
    [1]
    1. Hot-rolled steel sheet, characterized by the fact that it comprises:
    a chemical composition represented, in% by mass, by
    C: 0.02% to 0.15%,
    Si: 0.01% to 2.0%,
    Mn: 0.05% to 3.0%,
    P: 0.1% or less,
    S: 0.03% or less,
    Al: 0.001% to 0.01%,
    N: 0.02% or less,
    O: 0.02% or less,
    Ti: 0% to 0.2%,
    Nb: 0% to 0.2%,
    Mo: 0% to 0.2%,
    V: 0% to 0.2%,
    Cr: 0% to 1.0%,
    B: 0% to 0.01%,
    Cu: 0% to 1.2%,
    Ni: 0% to 0.6%,
    Ca: 0% to 0.005%,
    REM: 0% to 0.02%, and the balance: Fe and impurities; and a steel structure represented by a ferrite area ratio: 5% to 50%, a bainite area ratio composed of a bainitic ferrite aggregate whose average grain disorientation is 0.4 ° to 3 to 50% at 95 %, and a total area ratio of martensite, perlite, and austenite retained: 5% or less.
    [2]
    2. Hot rolled steel sheet according to the king
    2/2 vindication 1, characterized by the fact that the chemical composition satisfies one or more elements selected from the group consisting of, in% by mass,
    Ti: 0.01% to 0.2%,
    Nb: 0.01% to 0.2%,
    Mo: 0.001% to 0.2%,
    V: 0.01% to 0.2%,
    Cr: 0.01% to 1.0%,
    B: 0.0002% to 0.01%,
    Cu: 0.02% to 1.2%, and
    Ni: 0.01% to 0.6%.
    [3]
    3. Hot-rolled steel sheet according to claim 1 or claim 2, characterized by the fact that the chemical composition satisfies one or more elements selected from the group consisting of, in mass%,
    Ca: 0.0005% to 0.005% and
    REM: 0.0005% to 0.02%.
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    同族专利:
    公开号 | 公开日
    PL2987884T3|2019-07-31|
    CN105102658A|2015-11-25|
    CN105102658B|2017-03-15|
    TWI525201B|2016-03-11|
    US10000829B2|2018-06-19|
    ES2726654T3|2019-10-08|
    EP2987884A1|2016-02-24|
    KR101758003B1|2017-07-13|
    JP6194951B2|2017-09-13|
    EP2987884A4|2016-11-09|
    BR112015024840A2|2017-07-18|
    JPWO2014171427A1|2017-02-23|
    KR20150121161A|2015-10-28|
    MX2015013563A|2016-02-05|
    TW201502286A|2015-01-16|
    US20160017465A1|2016-01-21|
    EP2987884B1|2019-04-03|
    WO2014171427A1|2014-10-23|
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    法律状态:
    2018-11-13| B06F| Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]|
    2019-06-11| B07A| Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]|
    2019-09-10| B25D| Requested change of name of applicant approved|Owner name: NIPPON STEEL CORPORATION (JP) |
    2020-02-04| B09A| Decision: intention to grant [chapter 9.1 patent gazette]|
    2020-03-31| B16A| Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]|Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 14/04/2014, OBSERVADAS AS CONDICOES LEGAIS. |
    2022-02-08| B21F| Lapse acc. art. 78, item iv - on non-payment of the annual fees in time|Free format text: REFERENTE A 8A ANUIDADE. |
    优先权:
    申请号 | 申请日 | 专利标题
    JP2013-085009|2013-04-15|
    JP2013085009|2013-04-15|
    PCT/JP2014/060644|WO2014171427A1|2013-04-15|2014-04-14|Hot-rolled steel sheet|
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